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Title

Aza-Michael addition of chiral hydrazines to alkylidene malonates

AuthorsPrieto, María Auxiliadora ; Fernández, Rosario; Lassaletta, José M. ; Vázquez, Juan; Álvarez, Eleuterio
KeywordsConjugate addition
Hydrazines
Synthetic methods
Issue Date23-Mar-2005
PublisherElsevier
CitationTetrahedron 61(19): 4609-4613 (2005)
AbstractThe conjugate spontaneous addition of chiral N,N-dialkylhydrazines 1 to dimethyl alkylidene/arylidene malonates 2, 5–10 affords the corresponding β-hydrazino esters in moderate-to-good yields and selectivities. d-Mannitol-derived hydrazine 1a afforded best results, mainly due to the higher stability of the products 3, 11–16.
Description5 páginas, 2 figuras, 2 tablas, 3 esquemas.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2005.03.006
URIhttp://hdl.handle.net/10261/37877
DOI10.1016/j.tet.2005.03.006
ISSN0040-4020
Appears in Collections:(IIQ) Artículos
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