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Redox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexes

AuthorsCámpora, Juan ; Palma, Pilar ; Río, Diego del; López, Jorge A.; Álvarez, Eleuterio ; Connelly, Neil G.
KeywordsCationic palladium
Chemical oxidation
Issue Date23-Jun-2005
PublisherAmerican Chemical Society
CitationOrganometallics 24(15): 3624-3628 (2005)
AbstractA new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical analysis of these compounds reveals that the stability of the +4 oxidation state is sensitive to the electron-donor capability of the added co-ligand and to the steric features of the Tp‘ ligand.
Description5 páginas, 2 figuras, 2 tablas, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/om050216f
Appears in Collections:(IIQ) Artículos
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