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Title

Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes

AuthorsCámpora, Juan ; Matas, Inmaculada ; Palma, Pilar ; Graiff, Claudia; Tiripicchio, Antonio
KeywordsFluoride displacement
Lithium reagents
Synthesis
Nickel hydroxo
Alkoxo
Amido
β-hydrogen
Mononuclear Ni(II)
Issue Date6-May-2005
PublisherAmerican Chemical Society
CitationOrganometallics 24(12): 2827-2830 (2005)
AbstractThe complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li(OtBu), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by β-hydrogen elimination or disproportionation processes under mild conditions.
Description4 páginas, 2 figuras, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/om0489709
URIhttp://hdl.handle.net/10261/37768
DOI10.1021/om0489709
ISSN0276-7333
Appears in Collections:(IIQ) Artículos
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