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Title

Zincocenes as Mild Cyclopentadienyl Transfer Reagents toward Rhodium(I) Olefin Precursors. Facile Synthesis of (η5-Cp′)Rh(olefin)2 Compounds

AuthorsEsqueda Oliva, Ana Cristina ; Conejero, Salvador ; Maya, Celia ; Carmona, Ernesto
KeywordsOlefin
Zincocene
Benzene
Cyclopentadienyl complexes
Organometallic
Rhodium
Issue Date16-Dec-2008
PublisherAmerican Chemical Society
CitationOrganometallics 28(1): 45-47 (2009)
AbstractThe Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents.
Description3 páginas, 1 figura, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/om801046d
URIhttp://hdl.handle.net/10261/37700
DOI10.1021/om801046d
ISSN0276-7333
Appears in Collections:(IIQ) Artículos
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