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dc.contributor.authorPérez-Hernández, Natalia-
dc.contributor.authorFebles, M.-
dc.contributor.authorPérez, Cirilo-
dc.contributor.authorPérez, Ricardo-
dc.contributor.authorRodríguez, Matias L.-
dc.contributor.authorFoces-Foces, Concepción-
dc.contributor.authorMartín, Julio D.-
dc.date.accessioned2011-07-06T12:29:15Z-
dc.date.available2011-07-06T12:29:15Z-
dc.date.issued2006-01-10-
dc.identifier.citationJournal of Organic Chemistry 71(3): 1139-1151 (2006)es_ES
dc.identifier.issn0022-3263-
dc.identifier.other16438532-
dc.identifier.urihttp://hdl.handle.net/10261/37545-
dc.description13 páginas, 4 figuras, 1 tabla, 11 esquemas.es_ES
dc.description.abstractThe open-ended hollow tubular structure formed by inclusion of water molecules in the packing of the hydroxyl acid 1 (R1 = CH2OH, R2 = ethyl groups) led to the synthesis and structural study of their unsaturated analogues. In this article we report on a general and practical large-scale synthesis of hydroxyl acids that possess alkenyl and alkynyl appendages. Substitution of the ethyl groups in 1 with unsaturated two-carbon appendages has a different effect on the molecular structure and on the hydrogen-bonding pattern. No variation has been induced by substitution of only one ethyl group with a vinyl one, although the substitution of both ethyl groups with vinyl or acetylene appendages has the greatest effect on the molecular structure and results in different hydrogen-bonding motifs.es_ES
dc.description.sponsorshipFinancial support from the DGICYT of Spain through the CTQ2004-01674 project.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsclosedAccesses_ES
dc.subjectWateres_ES
dc.subjectHydroxyl acidses_ES
dc.subjectMolecular structurees_ES
dc.subjectAlkynyles_ES
dc.subjectHydrogen bondinges_ES
dc.subjectCarboxylic Acides_ES
dc.titleSynthesis and Structure of Hydroxyl Acids of General Structure 7,7-Alkenyl/alkynyl-5-hydroxymethyl-6-oxabicyclo[3.2.1]octane- 1-carboxylic Acides_ES
dc.typeartículoes_ES
dc.identifier.doi10.1021/jo052237p-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1021/jo052237pes_ES
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