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Imidazo[1,5-a]pyridine: A Versatile Architecture for Stable N-Heterocyclic Carbenes

AuthorsAlcarazo, Manuel; Rosedable, Stephen J.; Cowley, Andrew R.; Fernández, Rosario; Brown, John M.; Lassaletta, José M.
KeywordsN-heterocyclic carbenes
Mesoionic carbenes
Issue Date17-Feb-2005
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 127(10): 3290-3291 (2005)
AbstractThe imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
Description2 páginas, 1 figura, 2 tablas, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja0423769
Appears in Collections:(IIQ) Artículos
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