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Título: | Formation and Cleavage of C−H, C−C, and C−O Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals |
Autor: | Lara, Patricia CSIC ORCID; Paneque, Margarita CSIC ORCID; López Poveda, Manuel; Salazar, Verónica; López Santos, Laura; Carmona, Ernesto CSIC ORCID | Palabras clave: | ROAr Phenols Catalysts NMR spectroscopy Metals |
Fecha de publicación: | 25-feb-2006 | Editor: | American Chemical Society | Citación: | Journal of the American Chemical Society 128(11): 3512-3513 (2006) | Resumen: | 2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position. | Descripción: | 2 páginas, esquemas. | Versión del editor: | http://dx.doi.org/10.1021/ja0586790 | URI: | http://hdl.handle.net/10261/37478 | DOI: | 10.1021/ja0586790 | ISSN: | 0002-7863 |
Aparece en las colecciones: | (IIQ) Artículos |
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