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Title

Formation and Cleavage of C−H, C−C, and C−O Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals

AuthorsLara, Patricia ; Paneque, Margarita ; López Poveda, Manuel ; Salazar, Verónica; López Santos, Laura; Carmona, Ernesto
KeywordsROAr
Phenols
Catalysts
NMR spectroscopy
Metals
Issue Date25-Feb-2006
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 128(11): 3512-3513 (2006)
Abstract2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.
Description2 páginas, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja0586790
URIhttp://hdl.handle.net/10261/37478
DOI10.1021/ja0586790
ISSN0002-7863
Appears in Collections:(IIQ) Artículos
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