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Title

Transition Metal Migration upon Attempting the Wolff Rearrangement of an Ir(III) Five-Membered Metallacycle

AuthorsGómez, Margarita ; Paneque, Margarita ; López Poveda, Manuel ; Álvarez, Eleuterio
KeywordsIridium
Carbenes
Issue Date24-Apr-2007
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 129(19): 6092-6093 (2007)
AbstractOn attempting the Wolff rearrangement with an α-formyl-3-iridacyclopentanone, iridium migrates to the resulting carbene center in preference to carbon.
Description2 páginas, 3 figuras, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja070360n
URIhttp://hdl.handle.net/10261/37456
DOI10.1021/ja070360n
ISSN0002-7863
Appears in Collections:(IIQ) Artículos
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