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Rearrangement of Pyridine to Its 2-Carbene Tautomer Mediated by Iridium

AuthorsÁlvarez, Eleuterio ; Conejero, Salvador ; Lara, Patricia ; López, Jorge A.; Paneque, Margarita ; Guerreiro de Brito Petronilho, Ana Rita ; López Poveda, Manuel ; Río, Diego del; Serrano, Oracio; Carmona, Ernesto
2-Carbene Tautomer
Issue Date31-Oct-2007
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 129(46): 14130-14131 (2007)
AbstractOne of the Ir−CH2 bonds within the chelate structure of compound 1 acts as a C−H activation shuttle and permits the 1,2-H shift needed for the isomerization of pyridine to its 2-carbene tautomer. The iridium-mediated tautomerization is kinetically competitive with traditionally facile N coordination of the heterocycle.
Description2 páginas, 1 figura, esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja075685i
Appears in Collections:(IIQ) Artículos
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