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Title

Coupling Radical and Ionic Processes: An Unusual Rearrangement Affords Sugar and C-Glycoside Derivatives

AuthorsBoto, Alicia ; Hernández, Dácil ; Hernández, Rosendo ; Álvarez, Eleuterio
KeywordsRadical reactions
Rearrangement
Carbohydrates
Sequential processes
Photochemistry
Issue Date29-Jun-2009
PublisherWiley-VCH
CitationEuropean Journal of Organic Chemistry (23): 3853-3857 (2009)
AbstractAn unusual scission–rearrangement process, which couples radical and ionic reactions, was observed with galactofuranose derivatives. This one-pot procedure afforded, in good yields, highly functionalized 1,4-dioxanes, which could be considered as six-membered-ring sugar analogues. The synthesis of C-glycoside analogues is also possible with this methodology.
Description5 páginas, 2 figuras, 2 tablas, 6 esquemas.
Publisher version (URL)http://dx.doi.org/10.1002/ejoc.200900427
URIhttp://hdl.handle.net/10261/37217
DOI10.1002/ejoc.200900427
ISSN1434-193X
E-ISSN1099-0690
Appears in Collections:(IIQ) Artículos
(IPNA) Artículos
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