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C 2 -Symmetric S/C/S ligands based on N-heterocyclic carbenes: a new ligand architecture for asymmetric catalysis

AuthorsIglesias-Sigüenza, Javier; Ros, Abel ; Díez, Elena; Magriz, Antonio ; Vázquez, Arcadio ; Álvarez, Eleuterio ; Fernández, Rosario; Lassaletta, José M.
KeywordsN-heterocyclic carbenes
Asymmetric catalysis
Dipolar cycloaddition
Issue Date28-Aug-2009
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions (40) : 8485-8488 (2009)
AbstractNeutral, C2-symmetric S/C/S ligands based on N-heterocyclic carbenes and thioether functionalities were incorporated into transition metal complexes characterised by two direct metal-stereogenic sulfur bonds. This new ligand design was applied to 1,3-dipolar cycloadditions as the first example of the use silver of carbenes in asymmetric catalysis.
Description4 páginas, 3 figuras, 1 tabla, 3 esquemas.
Publisher version (URL)http://dx.doi.org/10.1039/B910846G
Appears in Collections:(IIQ) Artículos
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