English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36996
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates

AuthorsVargas Rodríguez, Sergio ; Suárez, Andrés ; Álvarez, Eleuterio ; Pizzano, Antonio
KeywordsAsymmetric catalysis
Hydrogention
P ligands
Rhodium
Issue Date24-Sep-2008
PublisherWiley-VCH
CitationChemistry - a European Journal 14(32): 9856-9859 (2008)
AbstractP–OP ′til you drop: Rhodium catalysts with chiral phosphane–phosphite ligands (P–OP) facilitate the enantioselective hydrogenation of β-acyloxy α,β-unsaturated phosphonates, affording β-acyloxyphosphonates in high enantiomeric excess (see scheme). These products can be easily converted into synthetically valuable β-hydroxyphosphonates without racemization.
Description4 páginas, 2 tablas, 6 esquemas. Corrected by: Corrigendum: Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates Vol. 16, Issue 33, 9937.
Publisher version (URL)http://dx.doi.org/10.1002/chem.200801588
URIhttp://hdl.handle.net/10261/36996
DOI10.1002/chem.200801588
ISSN0947-6539
E-ISSN1521-3765
Appears in Collections:(IIQ) Artículos
Files in This Item:
There are no files associated with this item.
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.