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http://hdl.handle.net/10261/36678
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Shin, Jiho | - |
dc.contributor.author | Kim, Seok Han | - |
dc.contributor.author | Camblor, Miguel Ángel | - |
dc.contributor.author | Warrender, Stewart J. | - |
dc.contributor.author | Miller, Stuart R. | - |
dc.contributor.author | Zhou, Wuzong | - |
dc.contributor.author | Wright, Paul A. | - |
dc.contributor.author | Hong, Suk Bong | - |
dc.date.accessioned | 2011-06-09T12:52:25Z | - |
dc.date.available | 2011-06-09T12:52:25Z | - |
dc.date.issued | 2010-01-12 | - |
dc.identifier.citation | Dalton Transactions | es_ES |
dc.identifier.uri | http://hdl.handle.net/10261/36678 | - |
dc.description | Supplementary material included at the end of the file. Material suplementario incluido al final del archivo. | es_ES |
dc.description.abstract | The synthetic details of a novel potassium gallosilicate natrolite with Si/Ga = 1.28, denoted PST-1, are described. The presence of K+ and Ga with well-defined levels of concentration in the synthesis mixture is essential for directing its crystallisation. PST-1 transforms rapidly into TNU-6 under hydrothermal conditions, behaviour that contrasts sharply with its very high thermal and hydrothermal stability, which is unusual for a material of such a high Ga content. These stability issues are discussed and rationalized based on chemical composition, likely violations of Loewenstein’s rule and the temperature of dehydration of as-made K-PST-1. The crystal structure of TNU-6 has been resolved through the combined use of synchrotron X-ray and electron diffraction data; it has the BaFeGaO4 structure type with an additional √3a x √3a “GeAlO4” superstructure that arises from tilting of some of the tetrahedral units in all of the 6-rings. | es_ES |
dc.description.abstract | Dalton Transactions 2010, 39, 2246-2253 | es_ES |
dc.description.sponsorship | KOSEF through the National Research Laboratory Program (R0A-2007-000-20050-0). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (UK) | es_ES |
dc.rights | openAccess | es_ES |
dc.subject | Potassium-gallosilicate-natrolite | es_ES |
dc.subject | Synthesis | es_ES |
dc.subject | In-situ-transformation | es_ES |
dc.subject | Thermal-hydrothermal-stability | es_ES |
dc.subject | Zeolites | es_ES |
dc.title | Synthesis and in situ transformation of PST-1: a potassium gallosilicate natrolite with a high Ga content | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1039/b920540n | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/b920540n | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ICMM) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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PST-1ms-DT-2010, 39, 2246-2253 DigitalCSIC.pdf | 1,33 MB | Adobe PDF | Visualizar/Abrir |
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