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Title

Organocatalytic Asymmetric Cyanosilylation of Nitroalkenes

AuthorsBernal, Pablo; Fernández, Rosario; Lassaletta, José M.
KeywordsAsymmetric catalysis
Bifunctional catalysis
Conjugate addition
Nitroalkenes
Organocatalysis
Synthetic methods
Issue Date8-Jun-2010
PublisherWiley-VCH
CitationChemistry - A European Journal 16(26): 7714-7718 (2010)
AbstractNew catalyst, new reaction: The unprecedented cyanosilylation of nitroalkenes can be efficiently catalyzed by a bifunctional quinine derivative with tetraalkylammonium cyanide and thiourea moieties. The activation of the nitroalkene by hydrogen bonding to the thiourea, together with the presence of an “active” cyanide, provides a new mode of activation that leads to products in high yields and good selectivities (see scheme).
Description5 páginas, 1 figura, 5 esquemas
Publisher version (URL)http://dx.doi.org/10.1002/chem.201001107
URIhttp://hdl.handle.net/10261/36513
DOI10.1002/chem.201001107
ISSN0947-6539
E-ISSN1521-3765
Appears in Collections:(IIQ) Artículos
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