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Title

Cyclometallation and Hydrogen/Deuterium Exchange Reactions of an Arylphosphine Ligand upon Coordination to {IrACHTUNGTRENUNG(h5-C5Me5)}

AuthorsCampos, Jesús ; Esqueda Oliva, Ana Cristina ; Carmona, Ernesto
KeywordsC-H activation
Irridium
Metallacycles
Phosphanes
Issue Date11-Jan-2010
PublisherWiley-VCH
CitationChemistry - A European Journal 16(2): 419-422 (2010)
AbstractWhich way to go? The cyclometallated compounds [(η5-C5Me5)Ir(X){PMe(2,6-CH2(Me)C6H3)(2,6-Me2C6H3)}] (X=Cl, H, Me) have been synthesized in high yields and their potential for C-H activation demonstrated. Deuterium incorporation into the metallated ligand backbone has been achieved for X=Cl and X=H, with dissimilar results and hence through different reaction pathways.
Description4 páginas, 4 esquemas
Publisher version (URL)http://dx.doi.org/10.1002/chem.200902791
URIhttp://hdl.handle.net/10261/36379
DOI10.1002/chem.200902791
ISSN1521-3765
E-ISSN0947-6539
Appears in Collections:(IIQ) Artículos
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