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dc.contributor.authorRivada-Wheelaghan, Orestes-
dc.contributor.authorDonnadieu, Bruno-
dc.contributor.authorMaya, Celia-
dc.contributor.authorConejero, Salvador-
dc.date.accessioned2011-06-01T08:34:25Z-
dc.date.available2011-06-01T08:34:25Z-
dc.date.issued2010-07-23-
dc.identifier.citationChemistry - A European Journal 16(24): 10323-10326 (2010)es_ES
dc.identifier.issn1521-3765-
dc.identifier.urihttp://hdl.handle.net/10261/36376-
dc.description5 páginas, 3 figuras, 5 esquemas.es_ES
dc.description.abstractPt to a T! Treating bulky N-heterocyclic carbene (NHC) ligands with [PtMe3I]4 results in rapid elimination of ethene and formation of [PtMeI(NHC)2] complexes. These complexes are suitable materials for the synthesis of T-shaped platinum(II) complexes stabilised by agostic interactions. X-ray structure determination of one of these complexes shows a rather long ζ agostic interaction.es_ES
dc.description.sponsorshipFinancial support from the Junta de Andalucía (project no. FQM-3151) and the Spanish Ministerio de Ciencia e Innovación (projects CTQ2007-62814 and CONSOLIDER-INGENIO 2010 CSD2007-00006, FEDER support) is acknowledged. O.R.-W. thanks the Spanish Ministerio de Ciencia e Innovación for a research grant.es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.relation.isversionofPreprint-
dc.rightsopenAccesses_ES
dc.subjectAgostic interactionses_ES
dc.subjectC-H activationes_ES
dc.subjectNitrogen heterocycleses_ES
dc.subjectPlatinumes_ES
dc.subjectT-shaped complexeses_ES
dc.titleT-Shaped Platinum(II) Complexes Stabilised by Bulky N-Heterocyclic Carbene Ligandses_ES
dc.typepreprintes_ES
dc.identifier.doi10.1002/chem.201000955-
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201000955es_ES
dc.identifier.e-issn0947-6539-
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