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dc.contributor.author | Rivada-Wheelaghan, Orestes | - |
dc.contributor.author | Donnadieu, Bruno | - |
dc.contributor.author | Maya, Celia | - |
dc.contributor.author | Conejero, Salvador | - |
dc.date.accessioned | 2011-06-01T08:34:25Z | - |
dc.date.available | 2011-06-01T08:34:25Z | - |
dc.date.issued | 2010-07-23 | - |
dc.identifier.citation | Chemistry - A European Journal 16(24): 10323-10326 (2010) | es_ES |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.uri | http://hdl.handle.net/10261/36376 | - |
dc.description | 5 páginas, 3 figuras, 5 esquemas. | es_ES |
dc.description.abstract | Pt to a T! Treating bulky N-heterocyclic carbene (NHC) ligands with [PtMe3I]4 results in rapid elimination of ethene and formation of [PtMeI(NHC)2] complexes. These complexes are suitable materials for the synthesis of T-shaped platinum(II) complexes stabilised by agostic interactions. X-ray structure determination of one of these complexes shows a rather long ζ agostic interaction. | es_ES |
dc.description.sponsorship | Financial support from the Junta de Andalucía (project no. FQM-3151) and the Spanish Ministerio de Ciencia e Innovación (projects CTQ2007-62814 and CONSOLIDER-INGENIO 2010 CSD2007-00006, FEDER support) is acknowledged. O.R.-W. thanks the Spanish Ministerio de Ciencia e Innovación for a research grant. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley-VCH | es_ES |
dc.relation.isversionof | Preprint | - |
dc.rights | openAccess | es_ES |
dc.subject | Agostic interactions | es_ES |
dc.subject | C-H activation | es_ES |
dc.subject | Nitrogen heterocycles | es_ES |
dc.subject | Platinum | es_ES |
dc.subject | T-shaped complexes | es_ES |
dc.title | T-Shaped Platinum(II) Complexes Stabilised by Bulky N-Heterocyclic Carbene Ligands | es_ES |
dc.type | preprint | es_ES |
dc.identifier.doi | 10.1002/chem.201000955 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/chem.201000955 | es_ES |
dc.identifier.e-issn | 0947-6539 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_816b | es_ES |
item.openairecristype | http://purl.org/coar/resource_type/c_816b | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | preprint | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
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T-Shaped.doc | 1,5 MB | Microsoft Word | Visualizar/Abrir |
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