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Título: | One-pot regioselective synthesis of 2I,3I-O-(o-xylylene)-capped cyclomaltooligosaccharides: tailoring the topology and supramolecular properties of cyclodextrins |
Autor: | Balbuena Olivia, Patricia; Lesur, David; González-Álvarez, M. José; Mendicuti, Francisco; Ortiz-Mellet, Carmen; García Fernández, José Manuel CSIC ORCID | Palabras clave: | α′-dibromo-o-xylylene Hydroxyls Glucopyranosyl Cyclodextrins Cyclomaltooligosaccharides |
Fecha de publicación: | 8-jun-2007 | Editor: | Royal Society of Chemistry (UK) | Citación: | Chemical Communications (31): 3270-3272 (2007) | Resumen: | The α,α′-dibromo-o-xylylene cap has been installed at the secondary hydroxyls of a single glucopyranosyl residue in cyclodextrins in one pot and with total regioselectivity; the resulting cyclic ether acts as a removable hinge, allowing selective elaboration of the secondary face and modulating both the self-association and the inclusion capabilities of the hosts. | Descripción: | 3 páginas, 3 figuras, 2 esquemas. | Versión del editor: | http://dx.doi.org/10.1039/B705644C | URI: | http://hdl.handle.net/10261/36338 | DOI: | 10.1039/B705644C | ISSN: | 1359-7345 |
Aparece en las colecciones: | (IIQ) Artículos |
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