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Title

Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes

AuthorsÁlvarez, Eleuterio ; Paneque, Margarita ; López Poveda, Manuel ; Rendón, Nuria
KeywordsAromaticity
C-C coupling
Iridium
Metallabenzenes
Metallacycles
Issue Date2-Dec-2005
PublisherWiley-VCH
CitationAngewandte Chemie - International Edition 45(3): 474-477 (2005)
AbstractA new synthesis of iridabenzene species involves the coupling of MeCH-CH2 with iridacycles 1 and 2. Surprisingly, the structure of the coupling product of the iridacyclopentadienes with propene (3 or 4) is highly susceptible to the nature of the substituents in the starting metallacycle.
Description4 páginas, figuras.
Publisher version (URL)http://dx.doi.org/10.1002/anie.200502437
URIhttp://hdl.handle.net/10261/36104
DOI10.1002/anie.200502437
ISSN1433-7851
E-ISSN1521-3773
Appears in Collections:(IIQ) Artículos
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