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Title

Cyclopentadienyl Zincates: Synthesis and X-ray Studies of Sodium and Potassium Salts of the [Zn(C5H5)3]− and [Zn2(C5H5)5]− Ions

AuthorsÁlvarez, Eleuterio ; Grirrane, Abdessamad; Resa, I.; Río, Diego del; Rodríguez, Amor ; Carmona, Ernesto
KeywordsAlkali metals
Density functional calculations
Metallocenes
Structure elucidation
Zinc
Issue Date5-Jan-2007
PublisherWiley-VCH
CitationAngewandte Chemie - International Edition 46(8): 1296-1299 (2007)
AbstractZigzag zinc: The Na+ and K+ salts of the [Zn(C5H5)3]− ion exhibit polymeric 1D and 2D structures, respectively. In contrast, the dizincate [Na(thf)6][Zn2(C5H5)5] contains discrete [Zn2(C5H5)5]− ions that consist of two {Zn(C5H5)2} groups with η1(π)/η1(π) binding, bridged by a C5H5 ring η1(π)-coordinated to each zinc atom (see structure).
Description4 páginas, figuras
Publisher version (URL)http://dx.doi.org/10.1002/anie.200603875
URIhttp://hdl.handle.net/10261/36100
DOI10.1002/anie.200603875
ISSN1433-7851
E-ISSN1521-3773
Appears in Collections:(IIQ) Artículos
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