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dc.contributor.authorDíez Gil, César-
dc.contributor.authorRatera, Immaculada-
dc.contributor.authorVeciana, Jaume-
dc.date.accessioned2011-05-13T08:47:14Z-
dc.date.available2011-05-13T08:47:14Z-
dc.date.issued2010-
dc.identifier.citationChemical Communications 47: 1842-1844 (2011)es_ES
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10261/35608-
dc.description.abstractThe rational design of a mercury(II) ligand consisting in a 1-(4′-oxyphenyl)-4(1′-pyrenyl)-2,3-diaza-1,3-butadiene receptor unit, optimizes the sensitivity and reliability of a SPR sensor by the formation of a well packed SAM over the gold surface. SPR analysis allows detecting mercury(II) concentrations in aqueous systems in the picomolar range, meliorating on three orders of magnitude the EU mercury(II) detection limit in drinkable water.es_ES
dc.description.sponsorshipThis work was supported by the Direccio´ n General de Investigacio´ n (Spain) (projects CTQ2006-06333/BQU and CTQ2008-01402), the Generalitat de Catalunya (projects 2009 SGR-00516 and XERMAE), Fundacio´n Se´neca (CARM, project 04509/GERM/06), and by CIBER-BBN, ISCIII. C.D. is grateful to MEC for a predoctoral grant.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.rightsclosedAccesses_ES
dc.subjectMercuryes_ES
dc.subjectDetectiones_ES
dc.titleSelective picomolar detection of mercury(II) using optical sensorses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/C0CC04860G-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c0cc04860ges_ES
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