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Título: | Enzymatic ring-opening polymerization of ε-caprolactone by Yarrowia lipolytica lipase in ionic liquids |
Autor: | Barrera-Rivera, Karla A.; Marcos-Fernández, Ángel CSIC ORCID ; Vera-Graziano, Ricardo; Martínez-Richa, Antonio | Palabras clave: | Ionic liquids Lipase ROP (ring-opening polymerization) Yarrowia lipolytica |
Fecha de publicación: | nov-2009 | Editor: | Wiley-Blackwell | Citación: | Journal of Polymer Science Part A: Polymer Chemistry 47(21): 5792-5805 (2009) | Resumen: | Yarrowia lipolytica (YLL), Candida rugosa (CRL), and porcine pancreatic lipase (PPL) were employed successfully as catalysts in the enzymatic ring-opening polymerization (ROP) of ε-caprolactone in the presence of 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]), 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]), 1-butylpyridinium tetrafluoroborate ([BuPy][BF4]), 1-butylpyridinium trifluoroacetate ([BuPy][CF3COO]), 1-ethyl-3-methylimidazolium nitrate ([EMIM][NO3]) ionic liquids. Poly(ε-caprolactone)s (PCLs) with molecular weights (Mn) in the range of 300–9000 Da were obtained. 1H- and 13C-NMR analyses on PCLs formed by YLL, CRL, and PPL showed asymmetric telechelic -hydroxy-ω-carboxylic acid end groups. Differences between CP-MAS and MAS spectra are observed and discussed in terms of morphology. MALDI-TOF spectra show the formation of at least seven species. Differential scanning calorimetry (DSC) and Wide Angle X-Ray Scattering (WAXS) results demonstrate the high degree of crystallinity present in all the polyesters. | Descripción: | 12 páginas, 17 figuras, 1 esquema, 2 tablas. | Versión del editor: | http://dx.doi.org/10.1002/pola.23623 | URI: | http://hdl.handle.net/10261/34488 | DOI: | 10.1002/pola.23623 | ISSN: | 0887-624X |
Aparece en las colecciones: | (ICTP) Artículos |
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