Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/34198
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Title

Crosslink reaction of natural rubber with thiuram sulphur donors in the presence of a thiuram monosulfide

AuthorsGonzález Hernández, Luis; Rodríguez Díaz, Andrés; Campo, Aránzazu del; Marcos-Fernández, Ángel CSIC ORCID CVN
KeywordsRubber
Crosslinking
Networks
Mechanical properties
Issue Date18-Jul-2002
PublisherWiley-Blackwell
CitationJournal of Applied Polymer Science 85(3): 491-499 (2002)
AbstractThe vulcanization of natural rubber was studied with the sulfurating agents dipentamethylene thiuram tetrasulfide (DPTT) and tetramethylene thiuram disulfide (TMTD) in the presence of tetramethyl thiuram monosulfide (TMTM). This last accelerant affects the rate and efficiency of the vulcanization as well as the structures of crosslinks formed by the two sulphur donors. It may give rise to a polymerization between adjacent double bonds and generate a inhomogeneous crosslink distribution with an adverse effect on physical properties.
Description9 páginas, 9 figuras, 5 tablas.
Publisher version (URL)http://dx.doi.org/10.1002/app.10438
URIhttp://hdl.handle.net/10261/34198
DOI10.1002/app.10438
ISSN0021-8995
Appears in Collections:(ICTP) Artículos

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