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Title

Palladium-catalyzed reduction of a propargylic acetate derived from a sugar with SmI2. Some unexpected

AuthorsMarco-Contelles, José ; Destabel, Christine; Chiara, José Luis
Issue Date1996
PublisherElsevier
CitationTetrahedron: Asymmetry 7(1): 105-108 (1996)
AbstractWe describe here the unexpected result that we have observed in the palladium-catalyzed reduction of the propargylic acetate 3 derived from a sugar with samarium diiodide. In addition to traces of the expected allene derived product 4, we have obtained mostly α-elimination leading to enynes 5 in moderate yield.
Description4 páginas, 3 esquemas.
Publisher version (URL)http://dx.doi.org/10.1016/0957-4166(95)00426-2
URIhttp://hdl.handle.net/10261/30923
DOI10.1016/0957-4166(95)00426-2
ISSN0957-4166
Appears in Collections:(IQOG) Artículos
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