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Synthesis of L-chiro-inositol and (−)-conduritol F from D -sorbitol by a highly stereoselective intramolecular pinacol coupling promoted by samarium diiodide

AuthorsChiara, José Luis ; Valle, Nuria
Issue DateAug-1995
CitationTetrahedron Asymmetry 6(8): 1895-1898 (1995)
AbstractA synthesis of L-chiro-inositol and (−)-conduritol F starting from readily available D -sorbitol is described. The route involves as a key step an efficient one-pot sequence consisting of the Swern oxidation of a 1,6-diol followed by a highly stereoselective intramolecular pinacol coupling of the resultant dialdehyde, promoted by samarium diiodide.
Description4 páginas, 1 figura.
Publisher version (URL)http://dx.doi.org/10.1016/0957-4166(95)00246-L
Appears in Collections:(IQOG) Artículos
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