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Título: | Ball-milling modification of single-walled carbon nanotubes: Purification, cutting, and functionalization |
Autor: | Rubio, Noelia; Fabbro, Chiara; Herrero, M. Antonia; Hoz, Antonio de la; Meneghetti, Moreno; García Fierro, José Luis CSIC ORCID; Prato, Maurizio; Vázquez, Ester | Fecha de publicación: | 2011 | Editor: | Wiley-VCH | Citación: | Small 7(5): 665-674 (2011) | Resumen: | Single-walled carbon nanotubes (SWNTs) can be successfully cut with relatively homogeneous sizes using a planetary mill. The optimized conditions produce highly dispersible SWNTs that can be efficiently functionalized in a variety of synthetic ways. As clearly shown by Raman spectroscopy, the milling/cutting procedure compares very favorably with the most common way of purifying SWNTs, namely, treatment with strong oxidizing acids. Moreover a similar milling process can be used to functionalize and cut pristine SWNTs by one-step nitrene chemistry. | URI: | http://hdl.handle.net/10261/281041 | DOI: | 10.1002/smll.201001917 | E-ISSN: | 1613-6810 |
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