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Título: | A conformationally restricted aspartic acid analogue |
Autor: | Buñuel, Elena; Cativiela, Carlos CSIC ORCID; Díaz de Villegas, María D. CSIC ORCID; Gálvez, José A. CSIC ORCID | Fecha de publicación: | 1996 | Editor: | International Union of Crystallography John Wiley & Sons |
Citación: | Acta Crystallographica - Section C - Crystal Structure Commun 52: 1252-1254 (1996) | Resumen: | In the title compound, (1R,2R,3S,4S)-3-benzamido-3-methoxycarbonylbicyclo[2.2.1]heptane-2-carboxylic acid, C17H19NO5, the norbornyl group shows distortion from C2v(mm2) symmetry of the parent hydrocarbon. The values determined for the torsion angles about the N-C[alpha] ([varphi]) and C[alpha]-CO ([psi]) bonds correspond to a semi-extended conformation for the amino acid residue. The structure is stabilized by an intermolecular O-H...O hydrogen bond between the carboxyl and amide groups and an intramolecular N-H...O hydrogen bond involving the benzamido and the carboxylic acid groups. | Versión del editor: | https://doi.org/10.1107/S0108270195016106 | URI: | http://hdl.handle.net/10261/270852 | DOI: | 10.1107/S0108270195016106 | ISSN: | 0108-2701 |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 59,24 kB | Adobe PDF | Visualizar/Abrir |
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