Adsorption of impurities from nickel-plating baths using commercial sorbents to reduce wastewater discharges

Abstract

The presence of moderate concentrations of impurities in the nickel-plating baths generates failures on the coated pieces. This situation entails the necessity of replacing the electroplating bath, which implies the generation of large volumes of wastewater with metallic species and high quantity of sludge. For this reason, the adsorption of the principal impurities of nickel-plating baths of an industry was analyzed in this work. Particularly, the removal of Zn2+ was studied in more detail since the presence of this metal in the baths generates black spots on the coated pieces. Different commercial materials were used as adsorbents and Zn2+ adsorption studies were carried out using both standard solutions and industrial water from the nickel-plating baths. All the adsorption tests were performed in batch systems under constant agitation and the quantification of the impurities was made by ICP-MS analysis. The bone char (BC) was an efficient adsorbent for the removal of the principal impurities of nickel-plating baths. The use of molecular simulation tools helped to understand the preferences of the hydroxyapatite (the principal component of bone char) for different metallic ions present in the industrial waters. According to both the experimental adsorption and molecular simulation results, hydroxyl and phosphate groups of bone char are responsible of the adsorption of impurities of nickel-plating baths.