Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/254457
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

A Concise Route to Water-Soluble 2,6-Disubstituted BODIPY-Carbohydrate Fluorophores by Direct Ferrier-Type C-Glycosylation

AuthorsGómez, Ana M. CSIC ORCID ; Uriel, Clara CSIC ORCID; Oliden-Sánchez, Ainhoa; Bañuelos, Jorge; Garcia-Moreno, I. CSIC ORCID; López, Cristóbal CSIC ORCID
Issue Date22-Jun-2021
PublisherAmerican Chemical Society
CitationJournal of Organic Chemistry 86(13): 9181–9188 (2021)
AbstractNovel, linker-free, BODIPY-carbohydrate derivatives containing sugar residues at positions C2 and C6 are efficiently obtained by, hitherto unreported, Ferrier-type C-glycosylation of 8- aryl-1,3,5,7-tetramethyl BODIPYs with commercially available tri-Oacetyl-D-glucal followed by saponification. This transformation, which involves the electrophilic aromatic substitution (SEAr) of the dipyrrin framework with an allylic oxocarbenium ion, provides easy access to BODIPY-carbohydrate hybrids with excellent photophysical properties and a weaker tendency to aggregate in concentrated water solutions
Description8 pags., 5 figs., 1 tab.
Publisher version (URL)https://doi.org/10.1021/acs.joc.1c00413
URIhttp://hdl.handle.net/10261/254457
DOI10.1021/acs.joc.1c00413
ISSN0022-3263
E-ISSN1520-6904
Appears in Collections:(IQFR) Artículos
(IQOG) Artículos

Files in This Item:
File Description SizeFormat
A Concise Route.pdfArtículo principal1,16 MBAdobe PDFView/Open
Supporting Information.pdfSupporting information3,17 MBAdobe PDFView/Open
Show full item record
Review this work

WEB OF SCIENCETM
Citations

2
checked on Nov 23, 2021

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.