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Título: | A dicoordinate gold(I)–ethylene complex |
Autor: | Navarro, Miquel; Miranda-Pizarro, Juan; Moreno, Juan J.; Navarro-Gilabert, Carlos; Fernández, Israel; Campos, Jesús CSIC ORCID CVN | Fecha de publicación: | 2021 | Editor: | Royal Society of Chemistry (UK) | Citación: | Chemical Communications, 57:9280 (2021) | Resumen: | The use of the exceptionally bulky tris-2-(4,40-di-tert-butylbiphenylyl) phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(I)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation of this species has been investigated by means of state-of-the-art Density Functional Theory (DFT) calculations indicating that p-backdonation plays a minor role compared with tricoordinate analogues | Versión del editor: | https://doi.org/10.1039/d1cc02769g | URI: | http://hdl.handle.net/10261/251090 | DOI: | 10.1039/d1cc02769g |
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