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Title

Synthesis of functionalized β-amino α,β-unsaturated esters and nitriles by nucleophilic vinylic substitution

AuthorsAncos, Begoña de CSIC ORCID ; Maestro, M. Carmen; Martin, M. Rosario; Fariña Pérez, Francisco
Issue Date1988
PublisherGeorg Thieme Verlag
CitationSynthesis 2: 136-138 (1988)
AbstractThe nucleophilic vinylic substitution of halogen by primary and secondary amines on methyl (E)- and (Z)-3-bromo-4,4-dimethoxy-2-butenoates (1) and the corresponding nitriles (2) leads to methyl 3-amino-4,4-dimethoxy-2-butenoates and the corresponding nitriles, respectively, in good yields. The stereochemistry of the reactions has also been studied.
Publisher version (URL)https://doi.org/10.1055/s-1988-27491
URIhttp://hdl.handle.net/10261/243934
DOIhttp://dx.doi.org/10.1055/s-1988-27491
ISSN0039-7881
Appears in Collections:(IQOG) Artículos
(ICTAN) Artículos
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