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Title

Short and Modular Synthesis of Substituted 2-Aminopyrroles

AuthorsDiana-Rivero, Raquel; Halsvik, Beate; García-Tellado, Fernando ; Tejedor, David
KeywordsHydrocarbons
Chemical reactions
Aromatic compounds
Rearrangement
Pyrroles
Issue Date30-Apr-2021
PublisherAmerican Chemical Society
CitationOrganic Letters 23(10): 4078–4082 (2021)
AbstractWe herein describe a simple and metal-free domino methodology to synthesize 2-aminopyrroles from alkynyl vinyl hydrazides. The domino reaction involves a novel propargylic 3,4-diaza-Cope rearrangement and a tandem isomerization/5-exo-dig N-cyclization reaction. By using this approach, a number of 2-aminopyrroles with diverse substituents have been prepared.
Publisher version (URL)https://doi.org/10.1021/acs.orglett.1c01345
URIhttp://hdl.handle.net/10261/240101
DOI10.1021/acs.orglett.1c01345
ISSN1523-7060
E-ISSN1523-7052
Appears in Collections:(IPNA) Artículos
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