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Título: | A fluorescent probe for alkanes, surfactants, lipids and self-organized molecular aggregates |
Autor: | Romero Giménez, Elena CSIC; Garriga, Rosa; Cebolla, Vicente L. CSIC ORCID CVN ; Galbán, Javier CSIC ORCID; Membrado, Luis CSIC ORCID; Muñoz, Edgar CSIC ORCID ; Jarne, Carmen CSIC ORCID | Palabras clave: | Fluorescence probes Low-toxic coralyne |
Fecha de publicación: | 8-sep-2014 | Citación: | IC3EM 2014 | Resumen: | Low-toxic coralyne, a cationic benzo[c]phenanthridine type alkaloid (Fig. 1), has received extensive attention because of its DNA- and RNA-targeting properties, and antimicrobial, anticancer activity, more pronounced compared to other protoberberine alkaloids [1-3]. In a previous work we showed that the fluorescence intensity alteration of coralyne-impregnated silica gel plates allows the sensitive quantitative detection of a wide number of analytes by high-performance thin layer chromatographic techniques [4]. It has been shown that coralyne cation undergoes self-aggregation in aqueous solutions by stacking interactions, even at low dye concentration, being the dimer less fluorescent than the monomer [5, 6]. In this work we have studied the influence of temperature in dimer formation. Due to its large flat aromatic structure, coralyne also has a high tendency to penetration into organized assemblies in solution with hydrophobic core such as micelles or liposomes, and we present here a fluorescence study of coralyne in different microheterogeneous media. Fluorescence emission increases when coralyne probe is situated in apolar microenvironments which prevent non-radiative desexcitation pahtways (Fig. 2). | Descripción: | 2 figures.-- Poster presented at the 1st International Caparica Conference on Chromagenic and Emissive Materials, IC3EM 2014, 8th-10th September, 2014, Caparica (Portugal). | URI: | http://hdl.handle.net/10261/234285 |
Aparece en las colecciones: | (ICB) Comunicaciones congresos |
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