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Title

Upconversion processes in Nd3+-doped fluoroarsenate glasses

AuthorsBalda, Rolindes CSIC ORCID; Lacha, L. M.; Mendioroz, A.; Sanz, M. CSIC ORCID; Fernández, Joaquín CSIC ORCID; Adam, J. L.; Arriandiaga, M. A.
Issue Date2001
PublisherElsevier
CitationJournal of Alloys and Compounds 323-324: 255-259 (2001)
AbstractIn this work we have studied the infrared to visible upconversion luminescence of Nd3+-doped fluoroarsenate glasses with different neodymium concentrations (0.1, 0.5, 2, 3, 4, and 5 mol%) under continuous wave and pulsed laser excitation. Green, orange, and red emissions are observed with excitation at 802 and 874 nm within the 4F5/2 and 4F3/2 levels. In addition, a weak blue emission appears under continuous wave (cw) laser excitation which under pulsed laser excitation only occurs for the most concentrated sample at 77 K. The green, orange, and red emissions can be attributed to transitions from the 4G7/2 excited state. The pump power dependencies of these upconverted emissions together with the shape of the upconverted excitation spectra which are similar to the one-photon absorption spectrum and the temporal behavior of the decays, indicate that an ETU process seems to be responsible for the observed visible luminescence, though other possible mechanisms cannot be disregarded.
Publisher version (URL)https://doi.org/10.1016/S0925-8388(01)01023-4
URIhttp://hdl.handle.net/10261/226246
DOIhttp://dx.doi.org/10.1016/S0925-8388(01)01023-4
ISSN0925-8388
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