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Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29

AuthorsSanz Aparicio, Julia; Martínez Carrera, Sagrario; García-Blanco, S.
Issue Date1986
PublisherWalter de Gruyter
CitationZeitschfrift für Kristallographie 175(3-4): 195-202 (1986)
AbstractMr = 460.36, monoclinic. P21/c, a = 13.718(1), b = 11.090(1), c = 14.985(1) Å, β = 98.162(2)°, V = 2256.67(9) Å3, Z = 4, Dx = 1.355 Mgm−3, μ = 0.933 mm−1, F(000) = 968, room temperature, final R = 0.047 (Rw = 0.048) for 3184 [I ⩾ 3 σ(I)] observed reflections. The title compound has the “three-legged piano stool” geometry, i.e. the coordination geometry of the iron can be regarded as a distorted octahedron with aη5 – C5Me5 group occupying three coordination sites. Like its nonmethylated analogue it contains an unusually monodentate dithiophosphate ester ligand.
Publisher version (URL)http://doi.org/10.1524/zkri.1986.175.3-4.195
Identifiersdoi: 10.1524/zkri.1986.175.3-4.195
issn: 0044-2968
Appears in Collections:(IQFR) Artículos
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