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A C(π-hole)⋯Cl-Zn tetrel interaction driving a metal-organic supramolecular assembly

AuthorsRamírez de Arellano, Carmen; Adam, Rosa; Ballesteros-Garrido, R.; Abarca, Belén; Ballesteros, Rafael; Alcorta, Ibon; Elguero, José CSIC ORCID; Escrivá, Emilio
Issue Date2020
PublisherRoyal Society of Chemistry (UK)
CitationCrystEngComm 22: 6979-6982 (2020)
AbstractA brominated pyrimidinyl triazolopyridine ligand (bptpy) forms a C(π-hole)⋯Cl-Zn tetrel interaction that plays a determining role in the formation of supramolecular layers through chain assembly in 18 membered metallacycle [(ZnCl2)2(μ-bptpy)2] crystals. Supramolecular chains are formed through C-H⋯X interactions. The observed interactions are supported by DFT calculations using model dimers. This journal is
Publisher version (URL)http://dx.doi.org/10.1039/d0ce01272f
Identifiersdoi: 10.1039/d0ce01272f
issn: 1466-8033
Appears in Collections:(IQM) Artículos
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