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Title

Catalytic enantioselective synthesis of a-aryl a-hydrazino esters and amides

AuthorsVelázquez, M.; Alberca, Saúl; Iglesias-Sigüenza, Javier; Fernández, Rosario; Lassaletta, José M. ; Monge, David
Issue Date2020
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 56: 5823- 5826 (2020)
AbstractCatalysts generated by combinations of Pd(TFA)and pyridine-hydrazone ligands have allowed the asymmetric 1,2-addition of aryl boronic acids toN-carbamoyl (Cbz and Fmoc) protected glyoxylate-derived hydrazones, yielding a-aryl a-hydrazino esters/amides in high enantioselectivities. Subsequent removal of the carbamoyl moiety affords key building blocks en route to hydrazinopeptides,N-aminopeptides and peptidomimetics thereof.
Publisher version (URL)http://dx.doi.org/10.1039/d0cc02478c
URIhttp://hdl.handle.net/10261/219719
Identifiersdoi: 10.1039/d0cc02478c
issn: 1364-548X
Appears in Collections:(IIQ) Artículos
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