Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/218871
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | A platinum molecular complex immobilised on the surface of graphene as active catalyst in alkyne hydrosilylation |
Autor: | Mollar-Cuni, Andrés; Borja, Pilar CSIC ORCID; Martín, Santiago CSIC ORCID; Guisado‐Barrios, Gregorio CSIC ORCID; Mata, José A. | Fecha de publicación: | 2020 | Editor: | Wiley-VCH | Citación: | European Journal of Inorganic Chemistry (45): 4254-426 (2020) | Resumen: | A platinum complex bearing a N‐heterocyclic carbene (NHC) ligand functionalised with a pyrene‐tag is immobilised onto the surface of reduced graphene oxide (rGO). The hybrid material composed of an organometallic complex and a graphene derivative is ready available in a single‐step process under mild reaction conditions. This methodology preserves the inherent properties of the active catalytic centre and the support. The platinum hybrid material is an efficient catalyst in hydrosilylation of alkynes and can be recycled and reused without significant loss of activity due to its high stability. Interestingly, the catalytic activity of the platinum complex is not affected by diffusion problems after immobilisation. The influence of graphene in hydrosilylation of alkynes is discussed in terms of activity and selectivity. | Descripción: | This article also appears in: Hot Topic: Carbon, Graphite, and Graphene Society Volumes: Spain. | Versión del editor: | https://doi.org/10.1002/ejic.202000356 | URI: | http://hdl.handle.net/10261/218871 | DOI: | 10.1002/ejic.202000356 | ISSN: | 1434-1948 | E-ISSN: | 1099-0682 |
Aparece en las colecciones: | (ICMA) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
platihydrosi.pdf | 1,47 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
6
checked on 20-mar-2024
WEB OF SCIENCETM
Citations
5
checked on 25-feb-2024
Page view(s)
173
checked on 28-mar-2024
Download(s)
133
checked on 28-mar-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.