Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/218811
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Elder T. | es_ES |
dc.contributor.author | Río Andrade, José Carlos del | es_ES |
dc.contributor.author | Rencoret, Jorge | es_ES |
dc.contributor.author | Kim, Hoon | es_ES |
dc.contributor.author | Beckham, Gregg T. | es_ES |
dc.contributor.author | Crowley, Michael F. | es_ES |
dc.date.accessioned | 2020-08-28T09:02:33Z | - |
dc.date.available | 2020-08-28T09:02:33Z | - |
dc.date.issued | 2020-07-09 | - |
dc.identifier.citation | ACS Sustainable Chemistry and Engineering 8(30): 11033–11045 (2020) | es_ES |
dc.identifier.uri | http://hdl.handle.net/10261/218811 | - |
dc.description | 13 páginas.- 8 figuras.- 3 tablas.- 63 referencias | es_ES |
dc.description.abstract | This perspective summarizes and compares computational results for the thermodynamics of bond dissociation, coupling, and rearomatization for a number of noncanonical lignin monomer–lignol combinations that have been found to occur experimentally. The noncanonical lignin monomers discussed are tricin, caffeyl alcohol, 5-hydroxyconiferyl alcohol, and piceatannol. Among dimeric combinations, the results for bond dissociation are generally similar, but in cases for which trimers have been reported (tricin-lignol adducts), this value can be quite variable, with stereochemical and structural preferences. Among the adducts examined thus far, the energies associated with quinone methide formation and rearomatization are not dissimilar and would not impede subsequent polymerization. These fundamental studies may help to elucidate how lignin monomers are incorporated into the lignin polymer, provide leads for targeted genetic modification, and be of use in deconstruction for the production of commodity chemicals. | es_ES |
dc.description.sponsorship | J. Re. and J.C.d.R. were funded by the Spanish Projects CTQ2014-60764-JIN and AGL2017-83036-R (financed by Agencia Estatal de Investigacion, AEI, and Fondo Europeo de Desarrollo Regional, FEDER). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-60764-JIN | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/AGL2017-83036-R | es_ES |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | en_EN |
dc.subject | Tricin | es_ES |
dc.subject | Piceatannol | es_ES |
dc.subject | Caffeyl alcohol | es_ES |
dc.subject | 5-Hydroxyconiferyl alcohol | es_ES |
dc.subject | Lignin | es_ES |
dc.title | Coupling and Reactions of Lignols and New Lignin Monomers: A Density Functional Theory Study | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/acssuschemeng.0c02880 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acssuschemeng.0c02880 | es_ES |
dc.identifier.e-issn | 2168-0485 | - |
dc.embargo.terms | 2021-07-09 | - |
dc.contributor.funder | Agencia Estatal de Investigación (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011033 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.contributor.orcid | Elder T. [0000-0003-3909-2152] | es_ES |
dc.contributor.orcid | Río Andrade, José Carlos del [0000-0002-3040-6787] | es_ES |
dc.contributor.orcid | Rencoret, Jorge [0000-0003-2728-7331] | es_ES |
dc.contributor.orcid | Kim, Hoon [0000-0001-7425-7464] | es_ES |
dc.contributor.orcid | Beckham, Gregg T. [0000-0002-3480-212X] | es_ES |
dc.contributor.orcid | Crowley, Michael F. [0000-0001-5163-9398] | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
Aparece en las colecciones: | (IRNAS) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Coupling_Reaction_ Lignols_New_Lignin_Monomers_Postprint.pdf | 1,69 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
11
checked on 23-mar-2024
WEB OF SCIENCETM
Citations
10
checked on 23-feb-2024
Page view(s)
184
checked on 28-mar-2024
Download(s)
123
checked on 28-mar-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.