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Title

Enhanced magnetism through oxygenation of FePc/Ag(110) monolayer phases

AuthorsBartolomé, Elena CSIC ORCID; Bartolomé, Juan CSIC ORCID; Sedona, Francesco; Lobo-Checa, Jorge CSIC ORCID ; Forrer, Daniel; Herrero-Albillos, Julia CSIC ORCID; Piantek, Marten CSIC; Herrero Martín, Javier CSIC ORCID; Betto, D.; Velez-Fort, E.; García, L. M. CSIC; Panighel, Mirko CSIC ORCID; Mugarza, Aitor CSIC ORCID; Sambi, Mauro; Bartolomé, Fernando CSIC ORCID
Issue Date2020
PublisherAmerican Chemical Society
CitationJournal of Physical Chemistry C 124(25): 13993–14006 (2020)
AbstractIron phthalocyanines (FePc) adsorbed onto a Ag(110) substrate self-assemble into different monolayer phases going from rectangular to different oblique phases, with increasing molecular density. We have investigated the oxygen uptake capability of the different phases and their associated magneto-structural changes. Our study combines scanning tunneling microscopy and spectroscopy (STM/STS), X-ray magnetic circular dichroism (XMCD), and density functional theory (DFT) calculations. STM measurements reveal that the oxygenation reaction of the FePc/Ag(110) generally involves a displacement and a rotation of the molecules, which affects the electronic state of the Fe centers. The oxygen intercalation between FePc and the substrate is greatly obstructed by the steric hindrance in the high-density phases, to the point that a fraction of oblique phase molecules cannot change their position after oxidizing. Depending on the oxidation state and adsoption geometry, the STS spectra show clear differences in the Fe local density of states, which are mirrored in the XAS and XMCD experiments. Particularly, XMCD spectra of the oxidized phases reflect the distribution of FePc species (nonoxygenated, oxygenated-rotated, and oxygenated-unrotated) in the different cases. Sum rule analysis yields the effective spin (mseff) and orbital (mL) magnetic moments of Fe in the different FePc species. Upon oxygenation, the magnetic moment of FePc molecules increases about an order of magnitude, reaching mTOT ∼ 2.2 μB per Fe atom.
Publisher version (URL)https://doi.org/10.1021/acs.jpcc.0c01988
URIhttp://hdl.handle.net/10261/218762
DOI10.1021/acs.jpcc.0c01988
ISSN1932-7447
E-ISSN1932-7455
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