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dc.contributor.authorMerino-Díez, Nestores_ES
dc.contributor.authorMohammed, Mohammed S. G.es_ES
dc.contributor.authorCastro-Esteban, Jesúses_ES
dc.contributor.authorColazzo, Lucianoes_ES
dc.contributor.authorBerdonces-Layunta, Alejandroes_ES
dc.contributor.authorLawrence, Jameses_ES
dc.contributor.authorPascual, José I.es_ES
dc.contributor.authorOteyza, Dimas G. dees_ES
dc.contributor.authorPeña, Diegoes_ES
dc.date.accessioned2020-08-26T06:46:08Z-
dc.date.available2020-08-26T06:46:08Z-
dc.date.issued2020-
dc.identifier.citationChemical Science 11(21): 5441-5446 (2020)es_ES
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10261/218626-
dc.descriptionThis article is part of the themed collection: 2020 Chemical Science HOT Article Collection.es_ES
dc.description.abstractFine management of chiral processes on solid surfaces has progressed over the years, yet still faces the need for the controlled and selective production of advanced chiral materials. Here, we report on the use of enantiomerically enriched molecular building blocks to demonstrate the transmission of their intrinsic chirality along a sequence of on-surface reactions. Triggered by thermal annealing, the on-surface reactions induced in this experiment involve firstly the coupling of the chiral reactants into chiral polymers and subsequently their transformation into planar prochiral graphene nanoribbons. Our study reveals that the axial chirality of the reactant is not only transferred to the polymers, but also to the planar chirality of the graphene nanoribbon end products. Such chirality transfer consequently allows, starting from adequate enantioenriched reactants, for the controlled production of chiral and prochiral organic nanoarchitectures with pre-defined handedness.es_ES
dc.description.sponsorshipWe acknowledge funding from the European Union's Horizon 2020 Programme (Grant Agreement No. 635919 (“SURFINK”) and 863098 (“SPRING”)), from the Spanish MINECO (Grant No. MAT2016-78293-C6), Xunta de Galicia (Centro singular de investigación de Galicia, accreditation 2016–2019, ED431G/09), and the Fondo Europeo de Desarrollo Regional (FEDER).es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/635919es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/863098es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-78293-C6es_ES
dc.relation.isversionofPublisher's versiones_ES
dc.rightsopenAccesses_ES
dc.titleTransferring axial molecular chirality through a sequence of on-surface reactionses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/D0SC01653E-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1039/D0SC01653Ees_ES
dc.identifier.e-issn2041-6539-
dc.rights.licensehttp://creativecommons.org/licenses/by-nc/3.0/es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderXunta de Galiciaes_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010801es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
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