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Título

XPS characterization of porous and sealed anodic films on aluminum alloys

AutorFeliú Jr., S.; Bartolomé, Mª. J.; González, J. A.; Feliú, S.
Palabras claveX-ray photoelectron spectra
Porous materials
Anodised layers
Aluminium
Metallic thin films
Aluminium alloys
Fecha de publicación16-mar-2007
EditorElectrochemical Society
CitaciónJournal of the electrochemical society 154(5): C241-C248 (2007)
ResumenThe present work uses X-ray photoelectron spectroscopy (XPS) to compare the chemical composition of the outer surface of porous and sealed anodic films on commercially pure Al and on Al–Cu, Al–Si–Mg, and Al–Mg alloy substrates. The study also considers some inner surfaces, obtained by mechanical abrasion and argon ion bombardment, in the bulk of porous and sealed anodic films on the Al–Mg alloy. The anodic films seem to be constituted mainly by pseudobohemite, with a uniform distribution of sulfate ions throughout the coating. Especially high O/Al ratio values have been determined on the outer surface of hydrothermally sealed films, which is interpreted as being due to the extra fixing of water and hydroxyl groups on the pseudobohemite.
Descripción8 pages.-- PACS: 82.80.Pv; 79.60.Bm
Versión del editorhttp://dx.doi.org/10.1149/1.2712148
URIhttp://hdl.handle.net/10261/21834
DOI10.1149/1.2712148
ISSN0013-4651
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