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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Godoy, Fernando | - |
dc.contributor.author | Oro, Luis A. | - |
dc.contributor.author | Klahn, A. Hugo | - |
dc.contributor.author | Lahoz, Fernando J. | - |
dc.contributor.author | Oelckers, Beatriz | - |
dc.date.accessioned | 2007-11-16T08:50:30Z | - |
dc.date.available | 2007-11-16T08:50:30Z | - |
dc.date.issued | 2004-06 | - |
dc.identifier.citation | Journal of the Chilean Chemical Society 3 (2004): 231-236 | en_US |
dc.identifier.issn | 0717-9707 | - |
dc.identifier.uri | http://hdl.handle.net/10261/2178 | - |
dc.description.abstract | The fulvene complex (η6-C5Me4CH2 )Re(CO)2(C6F5) 1a reacts with alkyl phosphines to yield the zwitterionic species (η5-C5Me4CH2 PR3)Re(CO)2(C6F 5) 2 (R = Me, Et, iPr). Reaction of the analogous iodo complex (η6-C5Me4CH2 )Re(CO)2I, 1b, with PMe3 and PEt3 affords the cationic species [(η5-C5Me4CH2 (PR3))Re(CO)2(PR3)] + I- 3 (R = Me, Et). However, reaction of 1b with Pi Pr3 yields the zwitterion (η5-C5Me4CH2 PiPr3)Re(CO)2 (I) 4. Trimethyl phosphite reacts with both 1a and 1b to afford the phosphonate complexes (η5-C5Me4CH2 P(O)(OMe)2)Re(CO)2(P(OMe) 3) 5a and trans-(η5C5Me4 CH2P(O)(OMe)2)Re(CO)2 (C6F5)(Me) 5b respectively. The complex [(η5-C5Me4CH2 (PMe3))Re(CO)2(PMe3 )]+ I- 3a has been characterized by X-ray structural analysis. | en_US |
dc.description.sponsorship | fulvene complexes, functionalized cyclopentadienyl complexes. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Sociedad Chilena de Química | en_US |
dc.rights | openAccess | en_US |
dc.subject | Fulvene complexes | en_US |
dc.subject | Functionalized cyclopentadienyl complexes | en_US |
dc.title | Reaction of Tetramenthylfulvene rhenium complexes (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) with alkyl phosphines and trimethylphosphosphite. X-Ray Structure of [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I- | en_US |
dc.type | artículo | en_US |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
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reaction.pdf | 370,39 kB | Adobe PDF | Visualizar/Abrir |
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