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Title

Triflyl-assisted reductive Pd-catalyzed Tsuji-Trost type reaction

AuthorsLázaro-Milla, Carlos; Quirós, M. Teresa; Cárdenas, D. J.; Almendros, Pedro
Issue Date2020
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 56: 6070-6073 (2020)
AbstractNew (triflyl)cyclobutenes have been prepared by palladium-catalyzed hydrodetriflylation reaction using water and deuterium oxide as convenient hydrogen and deuterium sources. In addition, an investigation of the possible mechanism for this Tsuji-Trost type reaction of bis(triflyl)cyclobutenes has been facilitated by labelling studies and density functional theory (DFT) calculations.
Publisher version (URL)http://dx.doi.org/10.1039/d0cc02146f
URIhttp://hdl.handle.net/10261/217855
DOIhttp://dx.doi.org/10.1039/d0cc02146f
Identifiersdoi: 10.1039/d0cc02146f
issn: 1364-548X
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