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Título

Highly excited vibrational states of HCN around 30 000 cm−1

AutorMartínez, Raúl Z. ; Lehmann, Kevin K.; Carter, Stuart
Palabras claveHydrogen compounds
Rotational-Vibrational energy transfer
Rotational-vibrational states
Vibration states
Fecha de publicación6-nov-2006
EditorAmerican Institute of Physics
CitaciónJournal of Chemical Physics 125(17): 174306 (2006)
ResumenThis article describes the analysis and interpretation of rovibrational spectra involving highly excited vibrational states in the molecule of HCN. The spectra were obtained by means of the vibrationally mediated photodissociation technique. Analysis of the spectra revealed four bands with - structures that, once fitted, provided the energies and rotational constants of four new, highly excited vibrational states in the region of the potential energy surface near and above 30 000 cm−1. All the states could be identified with the help of a state-of-the-art variational calculation. Together with the states already observed in previous works, eight highly excited states have so far been identified in this region.
Descripción4 pages, 4 figurers, 2 tables.-- PACS: 34.50.Ez; 33.20.Vq; 33.20.Sn; 34.20.Mq; 31.15.Pf; 33.80.Gj
Versión del editorhttp://dx.doi.org/10.1063/1.2387171
URIhttp://hdl.handle.net/10261/21730
DOI10.1063/1.2387171
ISSN0021-9606
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