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dc.contributor.authorObrero, José M.es_ES
dc.contributor.authorFilippin, Alejandro N.es_ES
dc.contributor.authorAlcaire, Maríaes_ES
dc.contributor.authorSánchez-Valencia, J. R.es_ES
dc.contributor.authorJacob, Martines_ES
dc.contributor.authorMatei, Constantines_ES
dc.contributor.authorAparicio, Francisco J.es_ES
dc.contributor.authorMacías-Montero, M.es_ES
dc.contributor.authorRojas, T. Cristinaes_ES
dc.contributor.authorEspinós, Juan P.es_ES
dc.contributor.authorSaghi, Zinebes_ES
dc.contributor.authorBarranco, Ángeles_ES
dc.contributor.authorBorrás, Anaes_ES
dc.date.accessioned2020-07-13T09:35:41Z-
dc.date.available2020-07-13T09:35:41Z-
dc.date.issued2020-
dc.identifier.citationFrontiers in Chemistry, 8 art.520 (2020)es_ES
dc.identifier.urihttp://hdl.handle.net/10261/216500-
dc.description.abstractThe large area scalable fabrication of supported porous metal and metal oxide nanomaterials is acknowledged as one of the greatest challenges for their eventual implementation in on-device applications. In this work, we will present a comprehensive revision and the latest results regarding the pioneering use of commercially available metal phthalocyanines and porphyrins as solid precursors for the plasma-assisted deposition of porous metal and metal oxide films and three-dimensional nanostructures (hierarchical nanowires and nanotubes). The most advanced features of this method relay on its ample general character from the point of view of the porous material composition andmicrostructure,mild deposition and processing temperature and energy constrictions and, finally, its straightforward compatibility with the direct deposition of the porous nanomaterials on processable substrates and device-architectures. Thus, taking advantage of the variety in the composition of commercially available metal porphyrins and phthalocyanines, we present the development of metal and metal oxides layers including Pt, CuO, Fe2O3, TiO2, and ZnO with morphologies ranging from nanoparticles to nanocolumnar films. In addition, we combine this method with the fabrication by low-pressure vapor transport of single-crystalline organic nanowires for the formation of hierarchical hybrid organic@metal/metal-oxide and @metal/metal-oxide nanotubes. We carry out a thorough characterization of the films and nanowires using SEM, TEM, FIB 3D, and electron tomography. The latest two techniques are revealed as critical for the elucidation of the inner porosity of the layers.es_ES
dc.language.isoenges_ES
dc.publisherFrontiers Mediaes_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/654360es_ES
dc.relation.isversionofPublisher's versiones_ES
dc.rightsopenAccesses_ES
dc.titleSupported Porous Nanostructures Developed by Plasma Processing of Metal Phthalocyanines and Porphyrinses_ES
dc.typeartículoes_ES
dc.identifier.doihttp://dx.doi.org/10.3389/fchem.2020.00520-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.3389/fchem.2020.00520es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
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