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A catalyst-free bis(triflyl)ethylation/benzannulation reaction: Rapid access to carbazole-based superacidic carbon acids from alkynols

AuthorsMartín-Mejías, I.; Aragoncillo, C.; Yanai, H.; Hoshikawa, S.; Fujimoto, Y.; Matsumoto, T.; Almendros, Pedro
Issue Date2020
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 56: 1795-1798 (2020)
AbstractCarbazoles possessing TfCHCH groups were obtained by the reaction of 1-(indol-2-yl)but-3-yn-1-ols with in situ-generated TfCCH through vicinal difunctionalisation of the alkyne moiety, where the vinyl-type carbocation intermediate was selectively attacked by the indole moiety and not by the carbanion moiety.
Publisher version (URL)http://dx.doi.org/10.1039/c9cc08930f
Identifiersdoi: 10.1039/c9cc08930f
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(IQOG) Artículos
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