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dc.contributor.authorSingh, Gurjaspreet-
dc.contributor.authorSaroa, Amandeep-
dc.contributor.authorPromila, Sunita Rania-
dc.contributor.authorChoquesillo-Lazarte, Duane-
dc.contributor.authorSahoo, Subash-
dc.date.accessioned2020-06-24T10:50:05Z-
dc.date.available2020-06-24T10:50:05Z-
dc.date.issued2017-05-01-
dc.identifierdoi: 10.1016/j.arabjc.2015.07.017-
dc.identifierissn: 1878-5352-
dc.identifier.citationArabian Journal of Chemistry 10 (4): 523-531 (2017)-
dc.identifier.urihttp://hdl.handle.net/10261/215120-
dc.description.abstractNew unsymmetrically Substituted Urea enclosed Silatranes (USUS) 2–5 are prepared in good yield by nucleophilic attack of pyrrolidine, piperidine, 3-methylpyridine-2-amine and N-methylbenzenamine containing active hydrogen atom on newly synthesized 3-isocyanatopropylsilatrane 1. All the compounds have been characterized by elemental analysis, IR, multinuclear (H and C) NMR and mass spectrometry. The single crystal X-ray crystallography technique facilitates the establishment of exact structures of silatranes 2, 3 and 4. The fluorescence titration results have revealed a selective on–off fluorescence response of silatranes toward acetate anion.-
dc.description.sponsorshipThe authors are grateful to UGC, New Delhi, India, for their financial support.-
dc.languageeng-
dc.publisherElsevier BV-
dc.relation.isversionofPublisher's version-
dc.rightsopenAccess-
dc.subjectSilatrane-
dc.subjectUrea-
dc.subjectIsocyanate-
dc.subjectFluorescence spectroscopy-
dc.subjectAnion sensor-
dc.titleUnsymmetrically urea silatranes: Synthesis, characterization and a selective on–off fluorescence response to acetate anion-
dc.typeartículo-
dc.identifier.doihttp://dx.doi.org/10.1016/j.arabjc.2015.07.017-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.arabjc.2015.07.017-
dc.date.updated2020-06-24T10:50:05Z-
dc.rights.licensehttps://creativecommons.org/licenses/by-nc-nd/4.0/-
dc.relation.csic-
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