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Title

Anharmonic potential functions as derived from Raman intensities: Methane

AuthorsBermejo, Dionisio ; Montero, Salvador
Issue Date1-Nov-1984
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 81: 3835-3841 (1984)
AbstractThe cubic force field of methane has been investigated on the basis of the analysis of Raman scattering cross sections of binary overtones and combination bands. Seven absolute cross sections, ten symmetry cubic force constants, and the second derivative of the mean CH bond polarizability are the original results of present work. Some of these cubic force constants are determined with high accuracy. Most Ĥ22 rovibrational constants calculated by means of present anharmonic force field are in good agreement with the experimental values reported by various authors. © 1984 American Institute of Physics.
Description7 pags., 2 figs., 5 tabs.
Publisher version (URL)http://dx.doi.org/10.1063/1.448166
URIhttp://hdl.handle.net/10261/214847
DOIhttp://dx.doi.org/10.1063/1.448166
Identifiersdoi: 10.1063/1.448166
issn: 0021-9606
Appears in Collections:(CFMAC-IEM) Artículos
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