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dc.contributor.author | Van-Schie, Morten | - |
dc.contributor.author | Zhang, Wuyuan | - |
dc.contributor.author | Tieves, Florian | - |
dc.contributor.author | Choi, D.S. | - |
dc.contributor.author | Park, Chan Beum | - |
dc.contributor.author | Burek, B.O. | - |
dc.contributor.author | Bloh, Jonathan Z. | - |
dc.contributor.author | Arends, I.W.C.E. | - |
dc.contributor.author | Paul, C.E. | - |
dc.contributor.author | Alcalde Galeote, Miguel | - |
dc.contributor.author | Hollmann, Frank | - |
dc.date.accessioned | 2020-06-16T08:30:05Z | - |
dc.date.available | 2020-06-16T08:30:05Z | - |
dc.date.issued | 2019 | - |
dc.identifier | doi: 10.1021/acscatal.9b01341 | - |
dc.identifier | issn: 2155-5435 | - |
dc.identifier.citation | ACS Catalysis 9: 7409- 7417 (2019) | - |
dc.identifier.uri | http://hdl.handle.net/10261/214468 | - |
dc.description.abstract | [EN] Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry. Instead of relying on complicated electron transport chains, they rely on simple hydrogen peroxide as the stoichiometric oxidant. Their poor robustness against HO can be addressed via in situ generation of HO. Here we report that simple graphitic carbon nitride (g-CN) is a promising photocatalyst to drive peroxygenase-catalyzed hydroxylation reactions. The system has been characterized by outlining not only its scope but also its current limitations. In particular, spatial separation of the photocatalyst from the enzyme is shown as a solution to circumvent the undesired inactivation of the biocatalyst. Overall, very promising turnover numbers of the biocatalyst of more than 60.000 have been achieved. | - |
dc.description.sponsorship | We thank The Netherlands Organization for Scientific Research for financial support through a VICI grant (No. 724.014.003) and by the European Union Project H2020-BBI-PPP-2015-2-720297-ENZOX2. CEP acknowledges a VENI grant (No. 722.015.011). | - |
dc.language | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/720297 | - |
dc.relation.isversionof | Publisher's version | - |
dc.rights | openAccess | - |
dc.subject | Cascade reactions | - |
dc.subject | Enzyme catalysis | - |
dc.subject | Oxidation | - |
dc.subject | Oxyfunctionalization | - |
dc.subject | Photocatalysis | - |
dc.title | Cascading g-C3N4 and Peroxygenases for Selective Oxyfunctionalization Reactions | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/acscatal.9b01341 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acscatal.9b01341 | - |
dc.date.updated | 2020-06-16T08:30:06Z | - |
dc.rights.license | This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. https://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html | - |
dc.contributor.funder | Netherlands Organization for Scientific Research | - |
dc.relation.csic | Sí | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
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Vam_Schie_Cascading_acscatal.9b01341.pdf | 2,07 MB | Adobe PDF | Visualizar/Abrir |
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