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Title

The microbiological transformation of a 9-epi-ent-pimaradiene diterpene by Gibberella fujikuroi

AuthorsFraga, Braulio M. ; González, Pedro; Hernández, Melchor G.; Chamy, María C.; Garbarino, Juan A.
KeywordsGibberella fujikuroi
Microbiological transformation
Diterpenes
9-epi-ent-pimarenes
Epoxidation
Issue Date1998
PublisherElsevier
CitationPhytochemistry 47(2): pp. 211-215 (1998)
AbstractIncubation of 2a, 19-dihydroxy-9-epi-ent-pimara-7.15-diene with the fungus Gibberella fujikuroi gave the compounds 2a, 19-dihydroxy-7a,8a-eposy-9-epi-ent-pimara-15-ene, 2a, 19-dihydroxy-7-oxo-9-epi-ent-pimara-15-ene. 2a, 19-dihydroxy-7-oxo-ent-pimara-8(9), 15-diene. 2a, 6$, 19-trihydroxy-7a, 8a-epoxy-9-epi-ent-pimara-15-ene, 2a.9$,19-trihydroxy-7a, 8a-epoxy-ent-pimara-15-ene, 2a, 7a, 8$, 19tetrahydroxy-9-epi-ent-pimara-15-ene and 2a, 7a, 9$, 19-tetrahydroxy-ent-pimara-15-ene. Oxidation of C-19, which is characteristic of the biosynthetic pathway of gibberellins, was nor observed.
URIhttp://hdl.handle.net/10261/21437
ISSN0031-9422
Appears in Collections:(IPNA) Artículos
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